{"id":489,"date":"2016-09-02T00:00:00","date_gmt":"2016-09-02T00:00:00","guid":{"rendered":"http:\/\/npaa.in\/journal-ijta\/spectroscopic-study-and-synthesis-of-schiffs-base-ligand-of-2-benzoylpyridine-semicarbazide-hydrochloride-and-its-cuii-and-niii-transition-metal-complexes\/"},"modified":"2019-09-23T06:15:13","modified_gmt":"2019-09-23T06:15:13","slug":"spectroscopic-study-and-synthesis-of-schiffs-base-ligand-of-2-benzoylpyridine-semicarbazide-hydrochloride-and-its-cuii-and-niii-transition-metal-complexes","status":"publish","type":"post","link":"https:\/\/npaa.in\/journal-ijta\/2016\/09\/02\/spectroscopic-study-and-synthesis-of-schiffs-base-ligand-of-2-benzoylpyridine-semicarbazide-hydrochloride-and-its-cuii-and-niii-transition-metal-complexes\/","title":{"rendered":"SPECTROSCOPIC STUDY AND SYNTHESIS OF SCHIFFS BASE LIGAND OF 2-BENZOYLPYRIDINE SEMICARBAZIDE HYDROCHLORIDE AND ITS Cu(II) AND Ni(II) TRANSITION METAL COMPLEXES"},"content":{"rendered":"<p>Sulekh Chandra, Meenakshi Gupta<\/p>\n<div style=\"text-align: justify;\"><b>ABSTRACT<\/b><\/div>\n<div style=\"text-align: justify;\">Transition metal complexes of Cu(II) and Ni(II) with 2-benzoylpyridinesemicarbazide hydrochloride with general composition ML2X2 (where M= Cu(II) and Ni(II), L= 2-benzoypyridine and semicarbazide hydrochloride ligand, X= Cl-,NO3-, SO42-, OAc- have been synthesised and characterised by elemental analysis, magnetic moment, conductivity measurement, mass spectrometry, IR spectrometry, UV-Vis spectroscopy, and EPR spectral studies. The magnetic moment values indicate that these are high spin complexes. The IR spectral study indicates that ligand is bidentate and coordinated through N and O. On the basis of spectral study Octahedral geometry was proposed for Ni(II) complexes and tetragonal geometry was proposed for Cu(II) complexes.<\/div>\n<div style=\"text-align: justify;\"><b><br \/><\/b><\/div>\n<div style=\"text-align: justify;\"><b>Keywords<\/b>: Semicarbazone,bidentate, Cu(II), Ni(II)<\/div>\n<div style=\"text-align: justify;\"><\/div>\n<p><a href=\"https:\/\/npaa.in\/journal-ijta\/admin\/ufile\/1473214457IJTA_33_33-39.pdf\">PDF<\/a><\/p>\n<p>\u00a0<\/p>\n<p>\u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Sulekh Chandra, Meenakshi Gupta ABSTRACT Transition metal complexes of Cu(II) and Ni(II) with 2-benzoylpyridinesemicarbazide hydrochloride with general composition ML2X2 (where &hellip; <\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[6,39],"tags":[],"class_list":["post-489","post","type-post","status-publish","format-standard","hentry","category-6","category-volume-33"],"_links":{"self":[{"href":"https:\/\/npaa.in\/journal-ijta\/wp-json\/wp\/v2\/posts\/489","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/npaa.in\/journal-ijta\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/npaa.in\/journal-ijta\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/npaa.in\/journal-ijta\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/npaa.in\/journal-ijta\/wp-json\/wp\/v2\/comments?post=489"}],"version-history":[{"count":2,"href":"https:\/\/npaa.in\/journal-ijta\/wp-json\/wp\/v2\/posts\/489\/revisions"}],"predecessor-version":[{"id":1165,"href":"https:\/\/npaa.in\/journal-ijta\/wp-json\/wp\/v2\/posts\/489\/revisions\/1165"}],"wp:attachment":[{"href":"https:\/\/npaa.in\/journal-ijta\/wp-json\/wp\/v2\/media?parent=489"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/npaa.in\/journal-ijta\/wp-json\/wp\/v2\/categories?post=489"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/npaa.in\/journal-ijta\/wp-json\/wp\/v2\/tags?post=489"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}